01576nas a2200181   4500000000100000008004100001100001800042700001800060700002000078700002200098700001800120700002100138245010400159300001400263490000700277520109600284020001401380       2018                            d1 aDebasis Nayak1 aTanmay Sarkar1 aVijay Chaudhary1 aMridula Bharadwaj1 aSudipto Ghosh1 aVenimadhav Adyam00aElectrochemical properties and first-principle analysisof Nax[MyMn1−y]O2 (M = Fe, Ni) cathode  a1079-10890 v223 aSodium-ion batteries are the commercially and environmentally viable next-generation candidates for automobiles. Structural and electrochemical aspects are greater concerns towards the development of a stable cathode material. Selecting transition metals and their composition greatly influences charge order, superstructures, and different voltage plateaus. This, in turn, influences transport properties and cyclic performance. This article aims to study the electrochemical performance, diffusivity, and structural stability of Nax[MyMn1−y]O2 (M = Fe, Ni) as cathode. Both experimental and DFT-based calculations apprehend the voltage plateaus due to redox reactions. The rate of cycling and the initial structure also influence the cycle life. The diffusion coefficient of P2-type Na0.67Fe0.5Mn0.5O2 for Mn3+/4+ redox reactions is more than that of the O3-type NaFe0.5Mn0.5O2 while it is less for Fe3+/4+ redox reactions, because of structural transition. The diffusion coefficient of NaNi0.5Mn0.5O2 is less for Ni2+/4+ redox reaction and is up to the order of 10−11 cm2 s−1.  a1433-0768